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Thursday, December 1, 2016

Classification of organic compounds

Acyclic or open chained compounds:
  • Also called aliphatic compounds.
  • Consist of straight or branched compounds.
Alicyclic or closed chained compounds:
  • Also called aliphatic cyclic.
  • Carbon atoms are bonded in the form of a ring.
  • Homocyclic - consisting only of carbon atoms joined in the ring.
  • Heterocyclic - consist of atoms other than carbon joined in the ring.
Aromatic compounds:
  • Benzenoid: These compounds consist of at least one benzene ring, i.e., a six-membered carbocyclic ring having alternate single and double bonds. Generally, these compounds have some fragrant odour and hence, named as aromatic (Greek word aroma meaning sweet smell).
  • Non-benzenoid aromatics: There are aromatic compounds, which have structural units different from benzenoid type and are known as Non-benzenoid aromatics
    Ex: Tropolone, azulene etc.
Functional group:
  • It is an atom or group of atoms responsible for the characteristic chemical properties of the compounds.Ex: (-OH) group - alcohol      (-CHO) group - aldehyde
Homologous series:
  • Compounds containing a common functional group.
  • The successive members differ by a –CH2 unit.Ex: alkanes - methane, ethane, propane
          Alkanols - methanol, ethanol, propanol

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